ORIGINAL ARTICLE
Adsorption of Polycyclic Aromatic Hydrocarbons (PAHS) from Aqueous Solutions on Different Sorbents
 
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1
Częstochowa University of Technology, Institute of Environmental Engineering, Poland
 
2
Częstochowa University of Technology, Department of Chemistry, Poland
 
 
Online publication date: 2014-12-10
 
 
Civil and Environmental Engineering Reports 2014;13(2):87-96
 
KEYWORDS
ABSTRACT
This paper presents the results of the possibility and effectiveness of PAHs removal from a model aqueous solution, during the sorption on the selected sorbents. Six PAHs (naphthalene, acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene) listed by EPA for the analysis in the environmental samples were determined. Model aqueous solution was prepared with RESTEK 610 mix PAHs standard. After the sorption process, decrease in the concentration of individual hydrocarbons was observed. The removal percentage was dependent on the type of sorbent (quartz sand, mineral sorbent, activated carbon). The highest efficiency (98.1%) was observed for activated carbon.. The results shows that the sorption processes can be used in aqueous solutions treatment procedures.
 
REFERENCES (26)
1.
Jones K.C. and De Voogt P.: Persistent organic pollutants (POPs): state of the science, Environmental Pollution 100.1 (1999) 209-221.
 
2.
Gajewska M., Kopeć Ł. and Obarska-Pempkowiak H.: Operation of Small Wastewater Treatment facilities in a Scattered Settlement. Rocznik Ochrona Środowiska (Annual Set the Environment Protection), 13, I (2011) 207-225.
 
3.
Włodarczyk-Makuła M.: Behaviour of PAHs during sewage sludge fermentation in the presence of sulphate and nitrate, Desalination and Water Treatment, 33(1-3) (2011) 178-184.
 
4.
Kowal A.L. and Świderska - Bróż M.: Water treatment. Theoretical background and technological processes and devices, Polish Scientific Publishers, Warszawa, 2007. (in polish).
 
5.
Oleszczuk P.: Organic Pollutats in sewage sludge-amended soil part II. Fate of contaminants soils, Ecological Chemistry and Engineering, 14(S2) (2007)185-198.
 
6.
Xu Z.R., Zhu W., Li M., Zhang H.W. and Gong M.: Quantitative analysis of polycyclic aromatic hydrocarbons in solid residues from supercritical water gasification of wet sewage sludge, Applied Energy, 102, (2013) 476-483.
 
7.
Wolska L.: Determination (monitoring) of PAHs in surface waters: why an operationally defined procedure is needed, Analytical and Bioanalytical Chemistry, 39 (208) 2647-2652.
 
8.
Hall s., Tang R., Baeyens J. and Dewil R.: Removing polycyclic aromatic hydrocarbons from water by adsorption on silicagel, Polycyclic Aromatic Compounds, 29(3) (2009) 160-183.
 
9.
Lach J., Okoniewska E., Neczaj E. and Kacprzak M.: The adsorption of Cr (III) and Cr (VI) on activated carbons in the presence of phenol, Desalination, 223(1) (2008) 249-255.
 
10.
Pranagal J. and Oleszczuk P.: Thepolycyclic aromatic hydrocarbons content in selected silty soils. Archiwum Ochrony Środowiska, 32, (2006) 69-80.
 
11.
Caban-Pabian B. Studies on self-purification of mining waters contaminated with polycyclic aromatic hydrocarbons, Archives of Environmental Protection, 28 (2008) 57-66.
 
12.
Kaleta J.: Removal of chosen organic pollutions from aqueous solutions in sorption process, Scientific Papers of Rzeszów University of Technology Civil and Environmental Engineering, 43 (241) (2007) 17-30 (in polish).
 
13.
Dąbek L. and Ozimina E.: Oxidation of organic contaminants adsorbed on activated carbons, Environmental Protection and Natural Resources, 41 (2009) 427-436.
 
14.
Valderrama C., Gamisans X., Cortina J.L., Farrran A. and De Las Heras F.X.: Evaluation of polyaromatic hydrocarbon removal from aqueous solutions using activated carbon and hyper-crosslinked polymer (Macronet MN200), Journal of Chemical Technology and Biotechnology, 84 (2009) 236—245.
 
15.
Ksycińska-Rębiś E., Lach J. and Okoniewska E.: The influence of carbon modification on the mechanism of phenol adsorption, Scientifical-Technical Conference: Activated carbon in environmental protection and industry, Częstochowa (2006) 160-168 (in polish).
 
16.
Chang C.F., Chang C.Y., Höll W., Ulmer M., Chen Y.H. and Groß H.J.: Adsorption kinetics of polyethylene glycol from aqueous solution onto activated carbon. Water Research, 38(10) (2004) 2559-2570.
 
17.
Müller S., Totsche K. and Kögel - Knabner I.: Sorption of polycyclic aromatic hydrocarbons to mineral surfaces, European Journal of Soil Science, 58(4) (2007) 918-931.
 
18.
Su Y.H., Zhu Y.G., Sheng G. and Chiou C.T.: Linear adsorption of nonionic organic compounds from water onto hydrophilic minerals: silica and alumina. Environmental science & technology, 40(22) (2006) 6949-6954.
 
19.
Li Y., Chen B., and Zhu L.: Enhanced sorption of polycyclic aromatic hydrocarbons from aqueous solution by modified pine bark, Bioresource technology, 101(19) (2010) 7307-7313.
 
20.
Pérez-Gregorio M.R., García-Falcón M.S., Martínez-Carballo E. and Simal-Gándara J.: Removal of polycyclic aromatic hydrocarbons from organic solvents by ashes wastes. Journal of hazardous materials, 178(1) (2010) 273281.
 
21.
Ali I. and Gupta V.K.: Advances in water treatment by adsorption technology, Nature Protocols, 1(6) (2007) 2661-2667.
 
22.
Macherzyński B. and Włodarczyk-Makuła M.: Extraction of PAH from Sewage Sludge from Coke Wastewater Separated, Inżynieria i Ochrona Środowiska, 4(14) (2011) 333-343 (in polish).
 
23.
Repelewicz M., Jedynak K. and Choma J.: Struktura porowata i chemia powierzchni węgli aktywnych modyfikowanych kwasami nieorganicznymi. Environmental Pollution Control, 3(31) (2009) 45-50 (in polish).
 
24.
Choma J, Jaroniec M., Burakiewicz-Mortka W. and Gwizdalski M.: Adsorption of Organic Compounds from Aqueous Solutions on Activated Carbon, Environmental Pollution Control, 1(56) (1995) 11-17.
 
25.
Smol M. and Włodarczyk-Makuła M.: Effectiveness in the removal of Polycyclic Aromatic Hydrocarbons from industrial wastewater by ultrafiltration technique, Archives of Environmental Protection, 38(4) (2012) 49-58.
 
26.
Włóka D., Kacprzak M., Rosikoń K. and Fijałkowski K.: Study of the migration of polycyclic aromatic hydrocarbons (PAH’s) in the sewage sludge-soil system, Environment Protection Engineering, 39(2) (2013) 113122.
 
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