Catalytic Oxidation of Pahs in Wastewater / Katalityczne Utlenianie Wwa w Ściekach
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Czestochowa University of Technology, Department of Chemistry Water and Wastewater Technology, Dąbrowskiego st 69, 42-200 Częstochowa, Poland
Online publication date: 2016-04-29
Publication date: 2016-03-01
Civil and Environmental Engineering Reports 2016;20(1):179–191
The aim of the investigations was to determine the effectiveness of the removal of 4, 5 - ring PAHs from coking wastewater using dihydrogen dioxide in the presence of a cobalt, platinum or titanium catalyst. A dose 7.4 mL of dihydrogen dioxide in the amount of and 14.8 mL/L of the analyzed sample were added to the samples. The samples were shaken and stored under laboratory conditions for 12 hours. The concentration of PAHs before and after the oxidation process were determined. The quantitative and qualitative chromatographic analysis was carried out using a gas chromatograph coupled with a mass spectrometer (GC-MS). The total concentration of 8 PAHs before oxidation reached the value of 9150 ng/L The concentration of 4-ring compounds and 5-ring PAHs were equal to 6390 ng/L and 2760 ng/L, respectively. The highest decrease (93%) the sum of 8 hydrocarbons using a dose of oxidizer 7.4 ml/L and in the presence of titanium catalyst was achieved.
Kupryszewski G.: Introduction to Organic Chemistry, Warsaw, Polish Scientific Publishers 1997 (in Polish).
Brown G. S., Barton L. L., Thomson B. M.: Permanganate oxidation of sorbed polycyclic aromatic hydrocarbons, Waste Management, 23 737-740 (2003).
Jamróz T., Ledakowicz S., Miller J., Sencio B.: Toxicity of polycyclic aromatic hydrocarbons and their decomposition products, Engineering and Chemical Apparatus, 3 45-46 (2002).
Young M. S., Mallet C. R., Mauro D., Fogel S., Jain A., Hoynak W.: The determination of anaerobic biodegradation products of aromatic hydrocarbons in groundwater using LC/MS/MS, ACS Symposium Series, 850, 325-337 (2003).
Wąsowski J., Piotrowska A.: The distribution of organic pollutants in water depth of oxidation processes, Environmental Protection, 2, 85 27-32 (2002).
Grzechulska-Damszel J., Orecki A., Mozik S., Tomaszewska M., Morawski A. W.: Opportunities and prospects for water and wastewater treatment in the system photocatalysis/membrane processes, Chemical Industry, 85 1011-1014 (2006).
Mielczarek K., Bohdziewicz J., Kwarciak-Kozłowska A.: Treatment of coke wastewater in the system combines integrated process of coagulation of the pressure membrane techniques, Annual Set The Environment Protection, 13, 1965-1984 (2011).
Mielczarek K., Bohdziewicz J., Kwarciak-Kozłowska A.: Comparison of the effectiveness of water treatment processes using coke coagulation and advanced oxidation, Environmental Engineering, 4, 184-194 (2011).
Turek A., Włodarczyk-Makuła M.: Removal of priority PAHs from coking wastewater, Civil and Environmental Engineering Reports, 10, 139-147 (2013).
Turek A., Włodarczyk-Makuła M.: Oxidation of low molecular weight PAHs in industrial wastewater, LAB Research Laboratory Apparatus, 17, 3, 14-17 (2012).
Turek A., Włodarczyk-Makuła M.: Removal of PAHs (C13-C16) from the coke wastewater using dihydrogen dioxide, in: Scientific Papers, series of Environmental Engineering, University of Zielona Góra, 25, 56-64 (2012).
Włodarczyk-Makuła M.: Quantitative changes of PAHs in treated sewage during oxidation, Annual Set The Environment Protection, 13, 2, 1093-1104 (2011).
Włodarczyk-Makuła M.: Quantitative Changes of PAHs in Wastewater Treatment and Sludge Processing,. Publisher of Czestochowa University of Technology, series of Monographs 126, Czestochowa 2007 (in Polish).
Zgirski A., Gondko R.: Obliczenia biochemiczne, PWN, Warszawa, 1998.
E.Ü. Gökhan, S. Kutlu, A. Akal Solmaz, A. Birgül, Regeneration of industrial district wastewater Rusing a combination of Fenton process and ion exchange- A case study, Resources, Conservation and Recycling, 52, 425-440 (2007).
Janiga M., Michniweicz M.: The use of hydrogen peroxide in the pretreatment process waters and effluents from the production of paper, IBWCh, a report from the first phase of work, designated P-22, Łódź 2007.
Lopez A., Pagano M., Volpe A., Di Pinto A. P.: Short Communication Fenton’s pre-treatment of mature landfill leachate, Chemosphere 54, 1005-1010 (2004).